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authentication failure

How do I support multiple ISP accounts (smarthost) in the Postfix SMTP client for relaying email? For example:

[a] user1@isp1.com must be relay via smtp.isp1.com.
[b] user1@isp2.com must be relay via smtp.isp2.com.
[c] me@mycorp.com must relay all my default email via smtp.mycorp.com.
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My ISP requires that mail from my dynamic IP to our small business email addresses uses their outgoing SMTP servers. This is probably done to reduce abuse and spam but now I'm not able to send email and local Postfix log file displays authentication failure message. How do I relay mail through my mail ISP servers using Postfix SMTP under Linux / UNIX like operating systems?
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Q. I've recently changed email user account password using passwd command, for one my postfix email server which requires SMTP authentication before sending an email. Now following error is logged into my /var/log/maillog file:

ERROR: Password not accepted from server: 535 5.7.0 Error: authentication failed: authentication failure

How do I solve this problem under Red Hat enterprise Linux running Postfix with SASL authentication?
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